# Asymmetric Hydrogenation and Catalysis

**Type:** Topics  
**Canonical URL:** https://scholariq.org/topics/asymmetric-hydrogenation-and-catalysis/

## Facts

| Field | Value |
| --- | --- |
| Description | This cluster of papers covers advances in homogeneous catalysis with transition metals, focusing on topics such as asymmetric catalysis, hydrogenation, chiral ligands, alcohol activation, dehydrogenation, amine synthesis, borrowing hydrogen, enantioselective reactions, and metal-ligand cooperation. |
| Domain | Physical Sciences |
| Field | Chemistry |
| OpenAlex ID | t11281 |
| Works | 25 |

## Topic papers all

Showing 15 of 25.

- [Transition metal-catalyzed ketone-directed or mediated C–H functionalization](https://scholariq.org/papers/transition-metal-catalyzed-ketone-directed-or-mediated-c-h-functionalization/)
- [Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions](https://scholariq.org/papers/chiral-monophosphorus-ligands-for-asymmetric-catalytic-reactions/)
- [Oxyanion Hole Stabilization by C–H···O Interaction in a Transition State—A Three-Point Interaction Model for<i>Cinchona</i>Alkaloid-Catalyzed Asymmetric Methanolysis of<i>meso</i>-Cyclic Anhydrides](https://scholariq.org/papers/oxyanion-hole-stabilization-by-c-h-o-interaction-in-a-transition-state-a-three/)
- [Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum](https://scholariq.org/papers/synthesis-of-molybdenum-and-tungsten-complexes-that-contain-triamidoamine/)
- [Monomeric Molybdenum and Tungsten Complexes That Contain a Metal–Phosphorus Triple Bond](https://scholariq.org/papers/monomeric-molybdenum-and-tungsten-complexes-that-contain-a-metal-phosphorus/)
- [Remarkable Electronic Effect on Rhodium-Catalyzed Carbonyl Additions and Conjugated Additions with Arylmetallic Reagents](https://scholariq.org/papers/remarkable-electronic-effect-on-rhodium-catalyzed-carbonyl-additions-and/)
- [Direct asymmetric aldol reactions between aldehydes and ketones catalyzed by l-tryptophan in the presence of water](https://scholariq.org/papers/direct-asymmetric-aldol-reactions-between-aldehydes-and-ketones-catalyzed-by-l/)
- [Manganese-Mediated Carbon−Carbon Bond Formation in Aqueous Media:  Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes](https://scholariq.org/papers/manganese-mediated-carbon-carbon-bond-formation-in-aqueous-media-chemoselective/)
- [Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes](https://scholariq.org/papers/transition-metal-catalysis-in-fluorous-media-application-of-a-new-immobilization/)
- [Gold supported on zirconia polymorphs for hydrogen generation from formic acid in base-free aqueous medium](https://scholariq.org/papers/gold-supported-on-zirconia-polymorphs-for-hydrogen-generation-from-formic-acid/)
- [Stereoconvergent, Redox‐Neutral Access to Tetrahydroquinoxalines through Relay Epoxide Opening/Amination of Alcohols](https://scholariq.org/papers/stereoconvergent-redox-neutral-access-to-tetrahydroquinoxalines-through-relay/)
- [Synergistic Catalysis for Promoting Ring-Opening Hydrogenation of Biomass-Derived Cyclic Oxygenates](https://scholariq.org/papers/synergistic-catalysis-for-promoting-ring-opening-hydrogenation-of-biomass/)
- [Enantioselective α-Allylation of Aryl Acetic Acid Esters via C1-Ammonium Enolate Nucleophiles: Identification of a Broadly Effective Palladium Catalyst for Electron-Deficient Electrophiles](https://scholariq.org/papers/enantioselective-allylation-of-aryl-acetic-acid-esters-via-c1-ammonium-enolate/)
- [Partially reduced iridium oxide clusters dispersed on titania as efficient catalysts for facile synthesis of dimethylformamide from CO <sub>2</sub> , H <sub>2</sub> and dimethylamine](https://scholariq.org/papers/partially-reduced-iridium-oxide-clusters-dispersed-on-titania-as-efficient/)
- [Enantioselective construction of nitrogen-substituted quaternary carbon centers adjacent to the carbonyl group in the cyclohexane ring: first asymmetric synthesis of anesthetic (S)-ketamine with high selectivity](https://scholariq.org/papers/enantioselective-construction-of-nitrogen-substituted-quaternary-carbon-centers/)

## Topic primary papers

- [Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions](https://scholariq.org/papers/chiral-monophosphorus-ligands-for-asymmetric-catalytic-reactions/)
- [Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum](https://scholariq.org/papers/synthesis-of-molybdenum-and-tungsten-complexes-that-contain-triamidoamine/)
- [Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes](https://scholariq.org/papers/transition-metal-catalysis-in-fluorous-media-application-of-a-new-immobilization/)
- [Stereoconvergent, Redox‐Neutral Access to Tetrahydroquinoxalines through Relay Epoxide Opening/Amination of Alcohols](https://scholariq.org/papers/stereoconvergent-redox-neutral-access-to-tetrahydroquinoxalines-through-relay/)
- [Enantioselective construction of nitrogen-substituted quaternary carbon centers adjacent to the carbonyl group in the cyclohexane ring: first asymmetric synthesis of anesthetic (S)-ketamine with high selectivity](https://scholariq.org/papers/enantioselective-construction-of-nitrogen-substituted-quaternary-carbon-centers/)
- [Promotional Effect of Cu for Catalytic Amination of Diethylene Glycol with Tertiarybutylamine over Ni–Cu/Al2O3 Catalysts](https://scholariq.org/papers/promotional-effect-of-cu-for-catalytic-amination-of-diethylene-glycol-with/)
- [Synthesis, structure and catalytic alcohol oxidation by ruthenium(III) supported by Schiff base and triphenylphosphine ligands](https://scholariq.org/papers/synthesis-structure-and-catalytic-alcohol-oxidation-by-ruthenium-iii-supported/)

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Source: ScholarIQ — public research metadata, principally OpenAlex. See https://scholariq.org/sources/ for provenance and https://scholariq.org/methodology/ for what these figures mean.