# Asymmetric Synthesis and Catalysis

**Type:** Topics  
**Canonical URL:** https://scholariq.org/topics/asymmetric-synthesis-and-catalysis/

## Facts

| Field | Value |
| --- | --- |
| Description | This cluster of papers covers recent advances in asymmetric catalysis, including organocatalysis, enantioselective reactions, chiral catalysts, asymmetric synthesis, C-C bond formation, spirooxindoles, hydrogen bonding, transition metal catalysis, quaternary stereocenters, and cascade reactions. |
| Domain | Physical Sciences |
| Field | Chemistry |
| OpenAlex ID | t10013 |
| Works | 30 |

## Topic papers all

Showing 15 of 30.

- [Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis](https://scholariq.org/papers/squaramides-bridging-from-molecular-recognition-to-bifunctional-organocatalysis/)
- [Cinchona Alkaloid Catalyzed Enantioselective Fluorination of Allyl Silanes, Silyl Enol Ethers, and Oxindoles](https://scholariq.org/papers/cinchona-alkaloid-catalyzed-enantioselective-fluorination-of-allyl-silanes-silyl/)
- [Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions](https://scholariq.org/papers/chiral-monophosphorus-ligands-for-asymmetric-catalytic-reactions/)
- [Recent advances in the synthesis of cyclopropanes](https://scholariq.org/papers/recent-advances-in-the-synthesis-of-cyclopropanes/)
- [Diastereo- and Atroposelective Synthesis of Bridged Biaryls Bearing an Eight-Membered Lactone through an Organocatalytic Cascade](https://scholariq.org/papers/diastereo-and-atroposelective-synthesis-of-bridged-biaryls-bearing-an-eight/)
- [Design and Synthesis of Chiral <i>oxa</i>-Spirocyclic Ligands for Ir-Catalyzed Direct Asymmetric Reduction of Bringmann’s Lactones with Molecular H<sub>2</sub>](https://scholariq.org/papers/design-and-synthesis-of-chiral-i-oxa-i-spirocyclic-ligands-for-ir-catalyzed/)
- [The Isolation of Three New Crystalline Antibiotics from Streptomyces<sup>1</sup>](https://scholariq.org/papers/the-isolation-of-three-new-crystalline-antibiotics-from-streptomyces-sup-1-sup/)
- [Remarkable Electronic Effect on Rhodium-Catalyzed Carbonyl Additions and Conjugated Additions with Arylmetallic Reagents](https://scholariq.org/papers/remarkable-electronic-effect-on-rhodium-catalyzed-carbonyl-additions-and/)
- [Chiral Phosphoric Acid Catalyzed Highly Enantioselective Desymmetrization of 2-Substituted and 2,2-Disubstituted 1,3-Diols via Oxidative Cleavage of Benzylidene Acetals](https://scholariq.org/papers/chiral-phosphoric-acid-catalyzed-highly-enantioselective-desymmetrization-of-2/)
- [Enantioselective α‐Benzylation of Acyclic Esters Using π‐Extended Electrophiles](https://scholariq.org/papers/enantioselective-benzylation-of-acyclic-esters-using-extended-electrophiles/)
- [Highly Enantioselective Nickel‐Catalyzed Intramolecular Reductive Cyclization of Alkynones](https://scholariq.org/papers/highly-enantioselective-nickel-catalyzed-intramolecular-reductive-cyclization-of/)
- [Desymmetrizing Enantio- and Diastereoselective Selenoetherification through Supramolecular Catalysis](https://scholariq.org/papers/desymmetrizing-enantio-and-diastereoselective-selenoetherification-through/)
- [Direct asymmetric aldol reactions between aldehydes and ketones catalyzed by l-tryptophan in the presence of water](https://scholariq.org/papers/direct-asymmetric-aldol-reactions-between-aldehydes-and-ketones-catalyzed-by-l/)
- [Manganese-Mediated Carbon−Carbon Bond Formation in Aqueous Media:  Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes](https://scholariq.org/papers/manganese-mediated-carbon-carbon-bond-formation-in-aqueous-media-chemoselective/)
- [Grignard-Type Carbonyl Phenylation in Water and under an Air Atmosphere](https://scholariq.org/papers/grignard-type-carbonyl-phenylation-in-water-and-under-an-air-atmosphere/)

## Topic primary papers

- [Squaramides: Bridging from Molecular Recognition to Bifunctional Organocatalysis](https://scholariq.org/papers/squaramides-bridging-from-molecular-recognition-to-bifunctional-organocatalysis/)
- [Enantioselective α‐Benzylation of Acyclic Esters Using π‐Extended Electrophiles](https://scholariq.org/papers/enantioselective-benzylation-of-acyclic-esters-using-extended-electrophiles/)
- [Direct asymmetric aldol reactions between aldehydes and ketones catalyzed by l-tryptophan in the presence of water](https://scholariq.org/papers/direct-asymmetric-aldol-reactions-between-aldehydes-and-ketones-catalyzed-by-l/)
- [Manganese-Mediated Carbon−Carbon Bond Formation in Aqueous Media:  Chemoselective Allylation and Pinacol Coupling of Aryl Aldehydes](https://scholariq.org/papers/manganese-mediated-carbon-carbon-bond-formation-in-aqueous-media-chemoselective/)
- [Grignard-Type Carbonyl Phenylation in Water and under an Air Atmosphere](https://scholariq.org/papers/grignard-type-carbonyl-phenylation-in-water-and-under-an-air-atmosphere/)
- [Enantioselective α-Allylation of Aryl Acetic Acid Esters via C1-Ammonium Enolate Nucleophiles: Identification of a Broadly Effective Palladium Catalyst for Electron-Deficient Electrophiles](https://scholariq.org/papers/enantioselective-allylation-of-aryl-acetic-acid-esters-via-c1-ammonium-enolate/)
- [Asymmetric Methallylation of Ketones Catalyzed by a Highly Active Organocatalyst 3,3′-F<sub>2</sub>-BINOL](https://scholariq.org/papers/asymmetric-methallylation-of-ketones-catalyzed-by-a-highly-active-organocatalyst/)
- [Development of a Large Scale Asymmetric Synthesis of the Glucocorticoid Agonist BI 653048 BS H<sub>3</sub>PO<sub>4</sub>](https://scholariq.org/papers/development-of-a-large-scale-asymmetric-synthesis-of-the-glucocorticoid-agonist/)
- [Palladium Catalyzed Alkoxy- and Aminocarbonylation of Vinyl Tosylates](https://scholariq.org/papers/palladium-catalyzed-alkoxy-and-aminocarbonylation-of-vinyl-tosylates/)
- [The First Asymmetric Pilot-Scale Synthesis of TV-45070](https://scholariq.org/papers/the-first-asymmetric-pilot-scale-synthesis-of-tv-45070/)
- [Multicomponent dipolar cycloadditions: efficient synthesis of polycyclic fused pyrrolizidines <i>via</i> azomethine ylides](https://scholariq.org/papers/multicomponent-dipolar-cycloadditions-efficient-synthesis-of-polycyclic-fused/)
- [Plant Process for the Preparation of Cinchona Alkaloid-Based Thiourea Catalysts](https://scholariq.org/papers/plant-process-for-the-preparation-of-cinchona-alkaloid-based-thiourea-catalysts/)
- [Stereodivergent Synthesis of Allylic All-Carbon Quaternary Centers by Bimetallic Iridium/Magnesium-Catalyzed Allylic Alkylation](https://scholariq.org/papers/stereodivergent-synthesis-of-allylic-all-carbon-quaternary-centers-by-bimetallic/)

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Source: ScholarIQ — public research metadata, principally OpenAlex. See https://scholariq.org/sources/ for provenance and https://scholariq.org/methodology/ for what these figures mean.