# Axial and Atropisomeric Chirality Synthesis

**Type:** Topics  
**Canonical URL:** https://scholariq.org/topics/axial-and-atropisomeric-chirality-synthesis/

## Facts

| Field | Value |
| --- | --- |
| Description | This cluster of papers focuses on the atroposelective synthesis of axially chiral compounds, exploring topics such as atropisomerism, asymmetric synthesis, catalytic reactions, enantioselective methods, and the use of chiral ligands. The research covers various techniques including Suzuki-Miyaura coupling, oxidative coupling, and organocatalysis. |
| Domain | Physical Sciences |
| Field | Chemistry |
| OpenAlex ID | t13115 |
| Works | 12 |

## Topic papers all

- [Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions](https://scholariq.org/papers/efficient-syntheses-of-korupensamines-a-b-and-michellamine-b-by-asymmetric/)
- [Diastereo- and Atroposelective Synthesis of Bridged Biaryls Bearing an Eight-Membered Lactone through an Organocatalytic Cascade](https://scholariq.org/papers/diastereo-and-atroposelective-synthesis-of-bridged-biaryls-bearing-an-eight/)
- [Design and Synthesis of Chiral <i>oxa</i>-Spirocyclic Ligands for Ir-Catalyzed Direct Asymmetric Reduction of Bringmann’s Lactones with Molecular H<sub>2</sub>](https://scholariq.org/papers/design-and-synthesis-of-chiral-i-oxa-i-spirocyclic-ligands-for-ir-catalyzed/)
- [Conversion of two stereocenters to one or two chiral axes: atroposelective synthesis of 2,3-diarylbenzoindoles](https://scholariq.org/papers/conversion-of-two-stereocenters-to-one-or-two-chiral-axes-atroposelective/)
- [The Acid Sphingomyelinase/Ceramide Pathway: Biomedical Significance and Mechanisms of Regulation](https://scholariq.org/papers/the-acid-sphingomyelinase-ceramide-pathway-biomedical-significance-and/)
- [Chiral Phosphoric Acid Catalyzed Highly Enantioselective Desymmetrization of 2-Substituted and 2,2-Disubstituted 1,3-Diols via Oxidative Cleavage of Benzylidene Acetals](https://scholariq.org/papers/chiral-phosphoric-acid-catalyzed-highly-enantioselective-desymmetrization-of-2/)
- [Highly Enantioselective Nickel‐Catalyzed Intramolecular Reductive Cyclization of Alkynones](https://scholariq.org/papers/highly-enantioselective-nickel-catalyzed-intramolecular-reductive-cyclization-of/)
- [Construction of Axially Chiral Compounds via Central‐to‐Axial Chirality Conversion](https://scholariq.org/papers/construction-of-axially-chiral-compounds-via-central-to-axial-chirality/)
- [Organocatalytic Enantioselective Synthesis of Seven‐Membered Ring with Inherent Chirality](https://scholariq.org/papers/organocatalytic-enantioselective-synthesis-of-seven-membered-ring-with-inherent/)
- [Asymmetric Methallylation of Ketones Catalyzed by a Highly Active Organocatalyst 3,3′-F<sub>2</sub>-BINOL](https://scholariq.org/papers/asymmetric-methallylation-of-ketones-catalyzed-by-a-highly-active-organocatalyst/)
- [Enantioselective construction of nitrogen-substituted quaternary carbon centers adjacent to the carbonyl group in the cyclohexane ring: first asymmetric synthesis of anesthetic (S)-ketamine with high selectivity](https://scholariq.org/papers/enantioselective-construction-of-nitrogen-substituted-quaternary-carbon-centers/)
- [Synthetic strategies based on aromatic metalation - cross coupling links. A concise formal synthesis of the azaphenanthrene alkaloid eupolauramine](https://scholariq.org/papers/synthetic-strategies-based-on-aromatic-metalation-cross-coupling-links-a-concise/)

## Topic primary papers

- [Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions](https://scholariq.org/papers/efficient-syntheses-of-korupensamines-a-b-and-michellamine-b-by-asymmetric/)
- [Diastereo- and Atroposelective Synthesis of Bridged Biaryls Bearing an Eight-Membered Lactone through an Organocatalytic Cascade](https://scholariq.org/papers/diastereo-and-atroposelective-synthesis-of-bridged-biaryls-bearing-an-eight/)
- [Design and Synthesis of Chiral <i>oxa</i>-Spirocyclic Ligands for Ir-Catalyzed Direct Asymmetric Reduction of Bringmann’s Lactones with Molecular H<sub>2</sub>](https://scholariq.org/papers/design-and-synthesis-of-chiral-i-oxa-i-spirocyclic-ligands-for-ir-catalyzed/)
- [Conversion of two stereocenters to one or two chiral axes: atroposelective synthesis of 2,3-diarylbenzoindoles](https://scholariq.org/papers/conversion-of-two-stereocenters-to-one-or-two-chiral-axes-atroposelective/)
- [Chiral Phosphoric Acid Catalyzed Highly Enantioselective Desymmetrization of 2-Substituted and 2,2-Disubstituted 1,3-Diols via Oxidative Cleavage of Benzylidene Acetals](https://scholariq.org/papers/chiral-phosphoric-acid-catalyzed-highly-enantioselective-desymmetrization-of-2/)
- [Construction of Axially Chiral Compounds via Central‐to‐Axial Chirality Conversion](https://scholariq.org/papers/construction-of-axially-chiral-compounds-via-central-to-axial-chirality/)
- [Organocatalytic Enantioselective Synthesis of Seven‐Membered Ring with Inherent Chirality](https://scholariq.org/papers/organocatalytic-enantioselective-synthesis-of-seven-membered-ring-with-inherent/)

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Source: ScholarIQ — public research metadata, principally OpenAlex. See https://scholariq.org/sources/ for provenance and https://scholariq.org/methodology/ for what these figures mean.