# Cyclopropane Reaction Mechanisms

**Type:** Topics  
**Canonical URL:** https://scholariq.org/topics/cyclopropane-reaction-mechanisms/

## Facts

| Field | Value |
| --- | --- |
| Description | This cluster of papers focuses on the catalytic carbene chemistry in organic synthesis, particularly on the use of donor-acceptor cyclopropanes, diazo compounds, and metal-catalyzed reactions. It covers topics such as enantioselective synthesis, site-selective functionalization, and the development of artificial metalloenzymes for carbene transfer reactions. |
| Domain | Physical Sciences |
| Field | Chemistry |
| OpenAlex ID | t11611 |
| Works | 18 |

## Topic papers all

Showing 15 of 18.

- [Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical](https://scholariq.org/papers/site-specific-allylic-c-h-bond-functionalization-with-a-copper-bound-n-centred/)
- [Highly Enantioselective Catalytic Fluorination and Chlorination Reactions of Carbonyl Compounds Capable of Two‐Point Binding](https://scholariq.org/papers/highly-enantioselective-catalytic-fluorination-and-chlorination-reactions-of/)
- [Recent advances in the synthesis of cyclopropanes](https://scholariq.org/papers/recent-advances-in-the-synthesis-of-cyclopropanes/)
- [Rhodium-Catalyzed Asymmetric C–H Functionalization Reactions](https://scholariq.org/papers/rhodium-catalyzed-asymmetric-c-h-functionalization-reactions/)
- [Facile Synthesis of Chiral α‐Difluoromethyl Amines from <i>N‐</i>(<i>tert</i>‐Butylsulfinyl)aldimines](https://scholariq.org/papers/facile-synthesis-of-chiral-difluoromethyl-amines-from-i-n-i-i-tert-i-2/)
- [I<sub>2</sub>/TBPB Mediated Oxidative Reaction of <i>N</i>-Tosylhydrazones with Anilines: Practical Construction of 1,4-Disubstituted 1,2,3-Triazoles under Metal-Free and Azide-Free Conditions](https://scholariq.org/papers/i-sub-2-sub-tbpb-mediated-oxidative-reaction-of-i-n-i-tosylhydrazones-with/)
- [Metallabenzene: synthesis, structure, and spectroscopy of a 1-irida-3,5-dimethylbenzene complex](https://scholariq.org/papers/metallabenzene-synthesis-structure-and-spectroscopy-of-a-1-irida-3-5/)
- [Ring-opening functionalizations of unstrained cyclic amines enabled by difluorocarbene transfer](https://scholariq.org/papers/ring-opening-functionalizations-of-unstrained-cyclic-amines-enabled-by/)
- [Copper-Catalyzed Tandem Azide–Alkyne Cycloaddition, Ullmann Type C–N Coupling, and Intramolecular Direct Arylation](https://scholariq.org/papers/copper-catalyzed-tandem-azide-alkyne-cycloaddition-ullmann-type-c-n-coupling-and/)
- [Gold-Catalyzed Sequential Alkyne Activation: One-Pot Synthesis of NH-Carbazoles via Cascade Hydroarylation of Alkyne/6-Endo-Dig Carbocyclization Reactions](https://scholariq.org/papers/gold-catalyzed-sequential-alkyne-activation-one-pot-synthesis-of-nh-carbazoles/)
- [Controlled Reversible Immobilization of Ru Carbene on Single-Walled Carbon Nanotubes: A New Strategy for Green Catalytic Systems Based on a Solvent Effect on π−π Interaction](https://scholariq.org/papers/controlled-reversible-immobilization-of-ru-carbene-on-single-walled-carbon/)
- [Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes](https://scholariq.org/papers/transition-metal-catalysis-in-fluorous-media-application-of-a-new-immobilization/)
- [A Modular Approach to the Synthesis of <i>gem</i>-Disubstituted Cyclopropanes](https://scholariq.org/papers/a-modular-approach-to-the-synthesis-of-i-gem-i-disubstituted-cyclopropanes/)
- [1,2:3,4:5,6-Tris(bicyclo\[2.2.2\]octeno)tropylium ion: an all-hydrocarbon carbocation with extraordinary stability](https://scholariq.org/papers/1-2-3-4-5-6-tris-bicyclo-2-2-2-octeno-tropylium-ion-an-all-hydrocarbon/)
- [Metal‐Free Decarboxylative Cyclization/Ring Expansion: Construction of Five‐, Six‐, and Seven‐Membered Heterocycles from 2‐Alkynyl Benzaldehydes and Cyclic Amino Acids](https://scholariq.org/papers/metal-free-decarboxylative-cyclization-ring-expansion-construction-of-five-six/)

## Topic primary papers

- [Recent advances in the synthesis of cyclopropanes](https://scholariq.org/papers/recent-advances-in-the-synthesis-of-cyclopropanes/)
- [A Modular Approach to the Synthesis of <i>gem</i>-Disubstituted Cyclopropanes](https://scholariq.org/papers/a-modular-approach-to-the-synthesis-of-i-gem-i-disubstituted-cyclopropanes/)
- [1,2:3,4:5,6-Tris(bicyclo\[2.2.2\]octeno)tropylium ion: an all-hydrocarbon carbocation with extraordinary stability](https://scholariq.org/papers/1-2-3-4-5-6-tris-bicyclo-2-2-2-octeno-tropylium-ion-an-all-hydrocarbon/)
- [Imidazoles as Serotonin Receptor Modulators for Treatment of Depression: Structural Insights and Structure–Activity Relationship Studies](https://scholariq.org/papers/imidazoles-as-serotonin-receptor-modulators-for-treatment-of-depression/)

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Source: ScholarIQ — public research metadata, principally OpenAlex. See https://scholariq.org/sources/ for provenance and https://scholariq.org/methodology/ for what these figures mean.